Communication: vacuum ultraviolet photoabsorption of interstellar icy thiols.
نویسندگان
چکیده
Following the recent identification of ethanethiol in the interstellar medium (ISM) we have carried out Vacuum UltraViolet (VUV) spectroscopy studies of ethanethiol (CH3CH2SH) from 10 K until sublimation in an ultrahigh vacuum chamber simulating astrochemical conditions. These results are compared with those of methanethiol (CH3SH), the lower order thiol also reported to be present in the ISM. VUV spectra recorded at higher temperature reveal conformational changes in the ice and phase transitions whilst evidence for dimer production is also presented.
منابع مشابه
Liquid-like behavior of UV-irradiated interstellar ice analog at low temperatures
Interstellar ice is believed to be a cradle of complex organic compounds, commonly found within icy comets and interstellar clouds, in association with ultraviolet (UV) irradiation and subsequent warming. We found that UV-irradiated amorphous ices composed of H2O, CH3OH, and NH3 and of pure H2O behave like liquids over the temperature ranges of 65 to 150 kelvin and 50 to 140 kelvin, respectivel...
متن کاملPhotoabsorption Spectroscopy in the Vacuum Ultraviolet: Measurements and Modeling of CO and CO2
High-resolution vacuum ultraviolet photoabsorption cross sections of CO2are required for modeling airglow emissions from the Martian and Venusian atmospheres and for photochemical models of those and Earth’s atmospheres. We report cross section measurements between 91000 and 115000 cm−1 (87–108 nm) at spectral resolutions of 1.15 cm−1 (91000 to 102000 cm−1) and 0.58 cm−1 (102000 to 115000 cm−1)...
متن کاملValence and ionic lowest-lying electronic states of ethyl formate as studied by high-resolution vacuum ultraviolet photoabsorption, He(I) photoelectron spectroscopy, and ab initio calculations.
The highest resolution vacuum ultraviolet photoabsorption spectrum of ethyl formate, C2H5OCHO, yet reported is presented over the wavelength range 115.0-275.5 nm (10.75-4.5 eV) revealing several new spectral features. Valence and Rydberg transitions and their associated vibronic series, observed in the photoabsorption spectrum, have been assigned in accordance with new ab initio calculations of...
متن کاملLimonene: electronic state spectroscopy by high-resolution vacuum ultraviolet photoabsorption, electron scattering, He(I) photoelectron spectroscopy and ab initio calculations.
Electronic state spectroscopy of limonene has been investigated using vacuum ultraviolet photoabsorption spectroscopy in the energy range 5.0-10.8 eV. The availability of a high resolution photon beam (~0.075 nm) enabled detailed analysis of the vibrational progressions and allowed us to propose, for the first time, new assignments for several Rydberg series. Excited states located in the 7.5-8...
متن کاملPhotoabsorption cross section measurements of CO2 between 106.1 and 118.7 nm at 295 and 195K
High-resolution vacuum ultraviolet carbon dioxide photoabsorption cross sections are required for modeling airglow emissions from the Martian and Venusian atmospheres and for photochemical models of those atmospheres. We report cross section measurements on CO2 at 295 and 195K between 106.1 and 118.7 nm at a spectral resolution of 0.005 nm. Significant deviations from the results of previous, l...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 141 23 شماره
صفحات -
تاریخ انتشار 2014